College football (6 p.m., ESPN): The season kicks off with South Carolina at Mississippi State.
MTV Video Music Awards (6 p.m., MTV): Jack Black hosts these always-goofy awards.
Big Brother All-Stars (7 p.m., Ch. 2): Another eviction.
Grey's Anatomy (7 and 8 p.m., Ch. 4): Two repeats of the show that had 11 Emmy nominations but won only one award — for casting.
The Office (7:30, 8 and 8:30 p.m., Ch. 5): Three repeats of the best-comedy Emmy winner.
Who Wants to Be a Superhero? (7 p.m., Sci Fi): A winner is declared.
Windfall (9 p.m., Ch. 5): This series started out strong in the ratings but then quickly collapsed, so this isn't the season finale — it's the series finale.