It's the fourth time for him, the second for her: Billionaire cosmetics executive Ron Perelman and actress Ellen Barkin are getting married.

"I'll confirm they'll be getting married but give no details in the interest of preserving their privacy," Perelman spokesman Howard Rubenstein said.

The New York Post reported that the Revlon mogul — still thick in the fight for custody of his 5-year-old daughter by third wife Patricia Duff — plans to marry Barkin on Wednesday at an East Side synagogue.

Perelman, who is worth almost $5 billion, has five other children and recently became a grandfather. He is 57.

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Barkin, 46, has two children with actor Gabriel Byrne.

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