It's all in the lips.

Angelina Jolie has been named the sexiest woman in the world by FHM magazine. It is Jolie's first time at the top of the annual readers' poll by the American edition of the men's magazine.

"Angelina Jolie embodies everything that our readers find incredibly sexy," editor in chief Scott Gramling said in a statement Wednesday. "Not only is she stunning, she is intelligent, outspoken and passionate in her beliefs and well-respected the world over for her tireless efforts on behalf of the world's refugee children."

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The 29-year-old actress is a goodwill ambassador for the U.N. refugee agency and the mother of Cambodia-born Maddox, whom she adopted. Jolie said she plans to adopt again and her son wants an "African brother."

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